Please do
  not follow the logic that retrieving user details from the Active Directory
  mentioned here, please visit my TechNet
  article for alternate approaches 
 | 
 
Last week,I prepared the small SharePoint utility to retrieving the Active Directory users and synchronize with SharePoint List.
public string LDAPUsers()
        {
            string listD = "";
            string strResult = "";
            string strRes = "";
            DirectoryEntry entry = new DirectoryEntry("LDAP://domainName", "userid", "pAsSwrd");
            DirectorySearcher mySearcher = new DirectorySearcher(entry);
            mySearcher.Filter = "((objectCategory=Person))";
            foreach (SearchResult resEnt in mySearcher.FindAll())
            {
                listD = listD + resEnt.GetDirectoryEntry().Name + ",";
            }
            string[] test = listD.Split('=');
            for (int i = 0; i < test.Length; i++)
            {
                strResult = strResult + test[i].ToString();
            }
            string[] test1 = strResult.Split(',');
            for (int j = 0; j < test1.Length; j++)
            {
                strRes = strRes + test1[j] + ",";
            }
            return strRes.Replace("CN", ""); ;
        }
Below code pushing the string array values in to SharePoint List.
SPSite site = new SPSite("http://moss:4100");
        SPWeb web = site.OpenWeb();
        SPList list = web.Lists["LDAP User"];
        string[] names = LDAPUsers().Split(',');
        for (int j = 0; j < names.Length; j++)
        {
            SPListItem item = list.Items.Add();
            web.AllowUnsafeUpdates = true;
            item["Title"] = names[j].ToString();
            web.AllowUnsafeUpdates = true;
            item.Update();
            web.AllowUnsafeUpdates = false;
        }